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Please use this identifier to cite or link to this item: http://hdl.handle.net/123456789/355

Title: Exploration of the Dynamical Evolution and the Associated Energetics of Water Nanoclusters Formed in a Hydrophobic Solvent
Authors: Mitra, Rajib Kumar
Verma, Pramod Kumar
Pal, Samir Kumar
Issue Date: 2009
Publisher: J. Phys. Chem.
Citation: R. K. Mitra, P. K.Verma and S. K. Pal, Exploration of the Dynamical the Associated Energetics of Water Nanoclusters formed in a Hydrophobic Solvent, J. Phys. Chem., B 113, (2009), 4744
Abstract: Exploration of the intermolecular binding energy in nanometer-sized small water clusters in hydrophobic solvents and its evolution with the increase in the cluster size until bulk-type geometry is reached constitute a fascinating area of research in contemporary chemical/biological physics. In this contribution we have used femtosecond/ picosecond-resolved solvation dynamics and fluorescence anisotropy techniques to explore the dynamical evolution of water clusters in dioxane continuum as a function of water concentration. We have also used temperature dependent picosecond-resolved solvation dynamics in order to explore the magnitude of the intermolecular bonding energy in the water clusters in bulk dioxane.
URI: http://hdl.handle.net/123456789/355
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